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• W2127623894 endingPage "2358" @default.
• W2127623894 startingPage "2355" @default.
• W2127623894 abstract "Abstract Highly activated thioesters formed by the rapid reaction of C‐terminal thioacids derived from protected amino acids and peptides with the Sanger reagent and other electron‐deficient aryl halides in the presence of a free amine immediately form a peptide bond with the amine. This essentially epimerization‐free method was used for the 4+4 block synthesis of a hindered octapeptide (see scheme; Boc, Pbf, and Trt are protecting groups). magnified image" @default.
• W2127623894 created "2016-06-24" @default.
• W2127623894 creator A5027175360 @default.
• W2127623894 creator A5080892892 @default.
• W2127623894 date "2009-03-10" @default.
• W2127623894 modified "2023-10-15" @default.
• W2127623894 title "Epimerization‐Free Block Synthesis of Peptides from Thioacids and Amines with the Sanger and Mukaiyama Reagents" @default.
• W2127623894 cites W1918431092 @default.
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• W2127623894 doi "https://doi.org/10.1002/anie.200805782" @default.
• W2127623894 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19229916" @default.
• W2127623894 hasPublicationYear "2009" @default.
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