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• W2127653815 abstract "A new procedure is proposed for determination of transference numbers from emf measurements. The procedure is applied to molten fluorides using literature data. We show that emf measurements reported for a cell containing NaF and AlF3 give transference numbers which are physically unlikely. The transference number reported for Na+, tNa−, in pure NaF is of no thermodynamic significance in the absence of pressure gradients. Data for the system NaF-AlF3Al2O3(sat) give the movement of one ion with respect to all others, and tNa+ is discussed for several choices of frame of reference. Inconsistency of some experimental results is pointed out. The thermodynamic significance of the findings is pointed out, and new experiments are suggested." @default.
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• W2127653815 date "1993-02-01" @default.
• W2127653815 modified "2023-10-13" @default.
• W2127653815 title "Transference coefficients and transference numbers in salt mixtures relevant for the aluminium electrolysis" @default.
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• W2127653815 doi "https://doi.org/10.1016/0013-4686(93)85159-v" @default.
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