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• W2127662789 abstract "The new ethanedithiolate-dimanganese carbonyl complex, Mn 2 (μ-SCH 2 CH 2 S)(CO) 7 , 1, was prepared in 28% yield from the reaction of 1,2,5,6-tetrathiacyclooctane with Mn 2 (CO) 9 (NCMe). Complex 1 was characterized crystallographically. It contains two Mn(CO) 3 groups joined by a Mn-Mn bond of 2.6470(6) A in length, a dihapto-bridging ethanedithiolate ligand, and one strong semibridging CO ligand. The reaction of 1 with PMe 2 Ph yielded two derivatives: Mn 2 (μ-SCH 2 CH 2 S)(CO) 6 (PMe 2 Ph), 2, and gem-Mn 2 (μ-SCH 2 CH 2 S)(CO) 5 (PMe 2 Ph) 2 , 3a, in 48% and 6% yields, respectively. When heated at 40 °C, compound 3a was transformed into three isomers, iso-gem-Mn 2 (μ-SCH 2 CH 2 S)(CO) 5 (PMe2Ph) 2 , 3b, 1,2-Mn 2 (μ-SCH 2 CH 2 S)(CO) 5 (PMe 2 Ph) 2 , 3c, and cis-Mn 2 (μ-SCH 2 CH 2 S)-(CO) 5 (PMe 2 Ph) 2 , 3d. Compounds 3b and 3c were characterized by single-crystal X-ray diffraction analyses. The introduction of phosphine ligand into the complexes strongly affects the semibridging character of the carbonyl ligand." @default.
• W2127662789 created "2016-06-24" @default.
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• W2127662789 date "2001-12-01" @default.
• W2127662789 modified "2023-10-14" @default.
• W2127662789 title "New evidence on the factors affecting bridging and semibridging character of carbonyl ligands. The structures of Mn₂(CO)₇(μ-SCH₂CH₂S) and its phosphine derivatives Mn₂(CO)_7-X(PMe₂Ph)_X(μ-SCH₂CH₂S), × = 1,2" @default.
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• W2127662789 doi "https://doi.org/10.1560/2ly5-kgwm-1je1-h1h0" @default.
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