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• W2127691411 abstract "Abstract The thermally unstable adduct TpMe2Ir(C2H4)(DMAD), which was generated “in situ” by the reaction of DMAD with TpMe2Ir(C2H4)2 (1) at low temperature, reacted with different carboxylic acids to produce the following compounds: TpMe2Ir(E-C(CO2Me) CH(CO2Me))(H2O)(OC(O)C6H4R), (R = H, 2a; o-OH, 2b; o-Cl, 2c; m-Cl, 2d; o-NO2, 2e; m-NO2, 2f; o-Me, 2g; p-Me, 2h) and TpMe2Ir(E-C(CO2Me) CH(CO2Me))(H2O)(OC(O)Me) 3. In the reaction of derivative 2a with Lewis bases, TpMe2Ir(E-C(CO2Me) CH(CO2Me))(L)(OC(O)C6H5), (L = Py, 4a; m-Br–Py, 4b; m-Cl–Py, 4c; NCMe, 5) were obtained, of which 4b and 4c were isolated as a mixture of two isomers in which the substituted pyridine ring was present at different rotational orientations. All new compounds prepared were characterized by 1H and 13C{1H} NMR spectroscopy, the structure of compounds 2d, 2h and 4a being determined by X-ray diffraction analysis. DFT was used to analyze the relative stability and the structural orientation of the isomers." @default.
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• W2127691411 date "2011-02-01" @default.
• W2127691411 modified "2023-10-18" @default.
• W2127691411 title "Reactivity of TpMe2Ir(C2H4)(DMAD) with carboxylic acids. A DFT study on geometrical isomers and structural characterization" @default.
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• W2127691411 doi "https://doi.org/10.1016/j.jorganchem.2010.09.073" @default.
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