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• W2127703040 abstract "We report atomic level high resolution transmission electron microscopy (HRTEM), electron nanodiffraction and nano-electron energy loss spectroscopy (nano-EELS) of boron-doped carbon nanostructures obtained by laser ablation of Co/Ni/B-doped carbon targets. The observations provide direct evidence for structural systematics and atomic structural defects as a function of the B content in the target. Targets with low B concentration (below 3 at%), produced ropes of single wall carbon nanotubes (SWCNTs) with no detectable boron present in the SWCNT ropes. However, unintended N-doping of the curved honeycomb lattice was observed in the 2.5 at% B sample (which is attributed to the possible presence of small amounts of N in the targets or reaction environments), with striking consequences for doping of heteroatoms within the hexagonal lattice of the graphene layer. At higher B concentration (3.5 at% and higher), there are significant changes in the nanostructure, which exhibits defective graphite layers and a small number of double wall carbon nanotubes (DWCNTs). At the higher B concentration, boron-doping is evidenced in the form of very small amorphous B clusters trapped in graphite-like defective sites." @default.
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• W2127703040 date "2004-01-01" @default.
• W2127703040 modified "2023-10-15" @default.
• W2127703040 title "Structural systematics in boron-doped single wall carbon nanotubes" @default.
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• W2127703040 doi "https://doi.org/10.1039/b311696d" @default.
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