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• W2127705199 abstract "The reduction behavior of two Ni, Fe-rich dioctahedral smectite clays has been investigated by temperature-programmed reduction (TPR). For both clays, the reduction process of the transition metal elements occurs in two steps. At about 400 degrees C, Fe3+ is first reduced to Fe2+. At higher temperatures, further reduction of iron and reduction of nickel are achieved. Samples reduced at 400 degrees C and 700 degrees C have been characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Mossbauer spectroscopy (MS), and transmission electron microscopy (TEM). After a treatment at 700 degrees C, metallic particles deposited on the silicates has been evidenced by TEM and confirmed with the other techniques. (C) 2000 Elsevier Science B.V. All rights reserved." @default.
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• W2127705199 date "2000-09-01" @default.
• W2127705199 modified "2023-09-24" @default.
• W2127705199 title "Nickel, iron-containing clay minerals from Niquelandia deposit, Brazil 2. Behaviour under reducing conditions" @default.
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• W2127705199 doi "https://doi.org/10.1016/s0169-1317(00)00013-2" @default.
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