FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2127706988> ?p ?o ?g. }

• W2127706988 endingPage "5832" @default.
• W2127706988 startingPage "5827" @default.
• W2127706988 abstract "Swift and energy efficient conversion of chemical feedstocks to pharmaceuticals and agrochemicals requires the development of new methods to add nitrogen functionality to unfunctionalized organic substrates. Dirhodium-catalyzed insertion of nitrene species into C-H bonds is a promising new method, the main drawback of which is the currently limited understanding of the catalytic mechanism. Herein, cyclic voltammetry and controlled potential electrolysis measurements have enabled us to solve many of the mechanistic mysteries of intermolecular C-H amination catalyzed by [Rh(2)(esp)(2)] (esp=α,α,α',α'-tetramethyl-1,3-benzenedipropanoate). The primary result is that, in addition to a simple nitrene-transfer mechanism that dominates the early stages of the reaction, another mechanism is available that relies on sequential proton-coupled electron transfer steps. Whereas the nitrene-transfer mechanism requires the use of expensive, atom-inefficient oxidants, we show that simple one-electron oxidants such as Ce(4+) may be used to achieve catalytic C-H amination via the one-electron mechanistic regime." @default.
• W2127706988 created "2016-06-24" @default.
• W2127706988 creator A5048296127 @default.
• W2127706988 creator A5084896370 @default.
• W2127706988 date "2011-04-19" @default.
• W2127706988 modified "2023-09-26" @default.
• W2127706988 title "Evidence for a One-Electron Mechanistic Regime in Dirhodium-Catalyzed Intermolecular CH Amination" @default.
• W2127706988 cites W1510912478 @default.
• W2127706988 cites W1964461178 @default.
• W2127706988 cites W1981072615 @default.
• W2127706988 cites W1984232099 @default.
• W2127706988 cites W1990957776 @default.
• W2127706988 cites W1996162362 @default.
• W2127706988 cites W2003754630 @default.
• W2127706988 cites W2006184470 @default.
• W2127706988 cites W2019568660 @default.
• W2127706988 cites W2025732472 @default.
• W2127706988 cites W2040789859 @default.
• W2127706988 cites W2045525404 @default.
• W2127706988 cites W2050876900 @default.
• W2127706988 cites W2052015737 @default.
• W2127706988 cites W2052859068 @default.
• W2127706988 cites W2061142370 @default.
• W2127706988 cites W2083150093 @default.
• W2127706988 cites W2088723766 @default.
• W2127706988 cites W2088943937 @default.
• W2127706988 cites W2092172784 @default.
• W2127706988 cites W2094642332 @default.
• W2127706988 cites W2102838682 @default.
• W2127706988 cites W2127953559 @default.
• W2127706988 cites W2131555480 @default.
• W2127706988 cites W2131939770 @default.
• W2127706988 cites W2133051795 @default.
• W2127706988 cites W2156843860 @default.
• W2127706988 cites W2162157647 @default.
• W2127706988 cites W2166144166 @default.
• W2127706988 cites W4242016959 @default.
• W2127706988 cites W4248729803 @default.
• W2127706988 cites W4251361927 @default.
• W2127706988 doi "https://doi.org/10.1002/chem.201100708" @default.
• W2127706988 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21506189" @default.
• W2127706988 hasPublicationYear "2011" @default.
• W2127706988 type Work @default.
• W2127706988 sameAs 2127706988 @default.
• W2127706988 citedByCount "64" @default.
• W2127706988 countsByYear W21277069882012 @default.
• W2127706988 countsByYear W21277069882013 @default.
• W2127706988 countsByYear W21277069882014 @default.
• W2127706988 countsByYear W21277069882015 @default.
• W2127706988 countsByYear W21277069882016 @default.
• W2127706988 countsByYear W21277069882017 @default.
• W2127706988 countsByYear W21277069882018 @default.
• W2127706988 countsByYear W21277069882019 @default.
• W2127706988 countsByYear W21277069882020 @default.
• W2127706988 countsByYear W21277069882021 @default.
• W2127706988 crossrefType "journal-article" @default.
• W2127706988 hasAuthorship W2127706988A5048296127 @default.
• W2127706988 hasAuthorship W2127706988A5084896370 @default.
• W2127706988 hasConcept C123669783 @default.
• W2127706988 hasConcept C147597530 @default.
• W2127706988 hasConcept C161790260 @default.
• W2127706988 hasConcept C166950319 @default.
• W2127706988 hasConcept C178790620 @default.
• W2127706988 hasConcept C185592680 @default.
• W2127706988 hasConcept C198503264 @default.
• W2127706988 hasConcept C21951064 @default.
• W2127706988 hasConcept C32909587 @default.
• W2127706988 hasConcept C38489247 @default.
• W2127706988 hasConcept C75473681 @default.
• W2127706988 hasConceptScore W2127706988C123669783 @default.
• W2127706988 hasConceptScore W2127706988C147597530 @default.
• W2127706988 hasConceptScore W2127706988C161790260 @default.
• W2127706988 hasConceptScore W2127706988C166950319 @default.
• W2127706988 hasConceptScore W2127706988C178790620 @default.
• W2127706988 hasConceptScore W2127706988C185592680 @default.
• W2127706988 hasConceptScore W2127706988C198503264 @default.
• W2127706988 hasConceptScore W2127706988C21951064 @default.
• W2127706988 hasConceptScore W2127706988C32909587 @default.
• W2127706988 hasConceptScore W2127706988C38489247 @default.
• W2127706988 hasConceptScore W2127706988C75473681 @default.
• W2127706988 hasIssue "21" @default.
• W2127706988 hasLocation W21277069881 @default.
• W2127706988 hasLocation W21277069882 @default.
• W2127706988 hasOpenAccess W2127706988 @default.
• W2127706988 hasPrimaryLocation W21277069881 @default.
• W2127706988 hasRelatedWork W2006184470 @default.
• W2127706988 hasRelatedWork W2025723876 @default.
• W2127706988 hasRelatedWork W2127706988 @default.
• W2127706988 hasRelatedWork W2131555480 @default.
• W2127706988 hasRelatedWork W2153701075 @default.
• W2127706988 hasRelatedWork W2950067753 @default.
• W2127706988 hasRelatedWork W2950135652 @default.
• W2127706988 hasRelatedWork W2951611895 @default.
• W2127706988 hasRelatedWork W3017120887 @default.
• W2127706988 hasRelatedWork W4210551422 @default.
• W2127706988 hasVolume "17" @default.
• W2127706988 isParatext "false" @default.
• W2127706988 isRetracted "false" @default.

• next