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- W2127777558 abstract "Abstract O-Acetyl-chitin was prepared in a lithium chloride-N,N-dimethylacetamide (LiCl/DMAc) system with high yield. The degree of acetylation was controlled with the amount of acetic anhydride. The obtained O-acetyl-chitin swelled not only in polar organic solvents, such as N,N-dimethylformamide (DMF) and dimethylsulfoxide (DMSO), but also in water. O-Acetyl-chitin powder was graft-copolymerized to methyl methacrylate without catalyst. Graft copolymerization was initiated by the photolysis of the O-acetyl-group and the polymerization in a Quartz tube proceeded easier than in a Pyrex tube. The addition of DMSO in the reaction system did not always accelerate the graft copolymerization. Effects of various factors such as monomer concentration, degree of substitution of the O-acetyl-group and polymer concentration were also investigated." @default.
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- W2127777558 date "1997-09-01" @default.
- W2127777558 modified "2023-09-23" @default.
- W2127777558 title "Non-catalytic photo-induced graft copolymerization of methyl methacrylate onto O-acetyl-chitin" @default.
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- W2127777558 doi "https://doi.org/10.1016/s0014-3057(97)00092-x" @default.
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