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- W2127840633 abstract "Abstract The new complex indium rhenium and scandium rhenium oxides, In 6 ReO 12 and Sc 6 ReO 12 , have been synthesized as single phases in sealed silica tubes and by high-pressure high-temperature syntheses, and their crystal structures have been determined by single crystal X-ray diffraction.The compounds crystallize in a rhombohedral structure related to the distorted fluorite structure like Ln 6 ReO 12 for some rare earth elements, S. G.: R -3, Z =3, a H = 9.248(2) A, c H =8.720(2) A for Sc 6 ReO 12 and a H =9.492(1) A, c H =8.933(1) A for In 6 ReO 12 . A maximum in magnetization is observed for Sc 6 ReO 12 at T ( M max )=1.89(2) K, whereas ferromagnetic ordering is found for In 6 ReO 12 by a pronounced increase in the temperature dependence of magnetization at T C =7.5(5) K. The magnetic moment per rhenium ion in In 6 ReO 12 and Sc 6 ReO 12 is 0.84(1) and 0.65(1) μ B , respectively, derived from the paramagnetic regions." @default.
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- W2127840633 date "2006-12-01" @default.
- W2127840633 modified "2023-10-11" @default.
- W2127840633 title "Synthesis, crystal structure and magnetic properties of new indium rhenium and scandium rhenium oxides, In6ReO12 and Sc6ReO12" @default.
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- W2127840633 doi "https://doi.org/10.1016/j.jssc.2006.07.041" @default.
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