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- W2127908798 abstract "Tris(9′,10′-dimethyl[9,10]ethanoanthracene[11′,12′: 1,9;11″,12″: 16,17;11′′′,12′′′: 30,31])[5,6]fullerene C60, the orthogonal (e,e,e)-tris-adduct of C60 and 9,10-dimethylanthracene, was obtained from [4+2]-cycloaddition (Diels–Alder reaction) at room temperature. The thermally unstable orange red (e,e,e)-tris-adduct was purified by chromatography and was isolated in the form of red monoclinic crystals. Its C3-symmetric addition pattern was established spectroscopically. Its structure could be further investigated by single crystal X-ray diffraction. The (e,e,e)-tris-adduct of C60 and 9,10-dimethylanthracene has earlier been suggested as intermediate and reversibly formed critical component in ‘template directed’ addition reactions of C60. This previously elusive compound has now been isolated and structurally characterized." @default.
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- W2127908798 date "2008-08-01" @default.
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- W2127908798 title "The Orthogonal (<i>e</i>,<i>e</i>,<i>e</i>)-Tris-Adduct of 9,10-Dimethylanthracene with C<sub>60</sub>-Fullerene: A Hidden Cornerstone of Fullerene Chemistry. Preliminary Communication" @default.
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- W2127908798 doi "https://doi.org/10.1002/hlca.200890152" @default.
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