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- W2127935500 abstract "Abstract Photoemission spectra (XPS and UPS) are presented for the valence band of misfit layer compounds (LnS) 1+ x TS 2 with Ln = Dy, Ho or Tb; T = Nb or Ta. The Nb 4d z 2 (or Ta 5d z 2 ) conduction band is almost filled, which indicates a charge transfer of slightly less than one electron per T from the LnS to the TS 2 layers. The spectra are similar to the spectrum of (LaS) 1.14 NbS 2 , except for the Ln 4f contribution. The rare-earth atoms in these compounds are trivalent. The localized 4f states shift about 2 eV to lower energy, as compared with the rare-earth metals. The electronic structure of the rare-earth misfit layer compounds is discussed." @default.
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- W2127935500 date "1997-05-01" @default.
- W2127935500 modified "2023-10-18" @default.
- W2127935500 title "Photoelectron spectra of the late rare-earth misfit layer compounds (LnS)1+xTS2 (Ln = Tb, Dy, Ho; T = Nb, Ta)" @default.
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- W2127935500 doi "https://doi.org/10.1016/s0921-4526(97)89578-6" @default.
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