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- W2127969373 abstract "The pore stability of styrene-divinylbenzene (S-DVB) copolymers prepared in toluene-cyclohexanol mixtures as inert diluents was investigated as a function of the DVB concentration, diluent composition, and dilution. The stability of the porous structures increases with increasing DVB concentration and, to some extent, with increasing dilution. At a fixed degree of equilibrium volume swelling in toluene, the pore stability also increases with increasing with increasing solvating power of the diluent. The density of S-DVB copolymers increases during the sulfonation reaction with chlorosulfonic acid, but the stability of porosity remains unchanged. Die Porenstabilität von Styrol-Divinylbenzol-Copolymeren (S-DVD), hergestellt in Toluol-Cyclohexanol-Mischungen, wurde in Abhängigkeit von der DVB-Konzentration, der Lösemittlezusammensetzung und der Verdünnung untersucht. Die Stabilität der Porenstrukturen nimmt mit steigender DVB-Konzentration zu und – in gewissem Ausmaß – auch mit steigender Verdünnung. Bei einem festgelegten Grad der Gleichgewichtsquellung in Toluol nimmt die Porenstabilität auch mit steigender Lösefähigkeit des Verdünnungsmittels zu. Die Dichte der S-DVB-Copolmeren steigt während der Sulfonierung mit Chlorsulfonsäure an, aber die Stabilität der Poren bleibt unverändert." @default.
- W2127969373 created "2016-06-24" @default.
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- W2127969373 date "1988-02-01" @default.
- W2127969373 modified "2023-10-17" @default.
- W2127969373 doi "https://doi.org/10.1002/apmc.1988.051570102" @default.
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