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- W2128085386 abstract "Abstract The transition metal‐catalyzed conjugate addition of organometallic reagents to electron‐deficient olefins is one of the most versatile methods for selective C ‐ C bond formation. The new iron‐catalyzed 1,6‐conjugate addition of aryl Grignard reagents to 2,4‐dienoates and ‐amides proceeded in a regio‐ and stereoselective manner gives virtually single cis‐olefinic adducts. As iron is an inexpensive, non‐toxic, and ubiquitous metal, this process fulfills the recent demand for an environmentally friendly process." @default.
- W2128085386 created "2016-06-24" @default.
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- W2128085386 date "2014-05-15" @default.
- W2128085386 modified "2023-10-14" @default.
- W2128085386 title "Iron‐Catalyzed Selective Conjugate Addition of Aryl Grignard Reagents to 2,4‐Alkadienoates: <i>tert</i> ‐Butyl ( <i>Z</i> )‐5‐Phenyl‐3‐hexenoate" @default.
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- W2128085386 doi "https://doi.org/10.1002/0471264229.os091.27" @default.
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