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- W2128343667 abstract "Die Zustandsdiagramme der pseudobinaren Systeme ACl/DyCl3 (A = Cs, Rb, K) wurden mittels DTA untersucht. Es existieren mit allen Alkalimetallen Verbindungen A3DyCl6 (Elpasolithfamilie) und Ady2Cl7 sowie Verbindungen A2DyCl5 mit A = Cs (Cs2DyCl5-Typ) und A = K (K2PrCl5-Typ). Von allen Verbindungen wurden uber Losungswarmen die Bildungsenthalpien aus (nACl + DyCl3) bestimmt und daraus ‘Synproportionierungsenthalpien’ fur die Bildung aus den im Zustandsdiagramm benachbarten Verbindungen berechnet. Nur K3DyCl6 bildet sich aus den Nachbarn unter Verlust an Gitterenthalpie. EMK = f(T)Messungen zeigen, das diese Verbindung oberhalb 39°C durch Entropiegewinn stabilisiert ist. Ahnlich grose Entropiegewinne treten auch bei den anderen Verbindungen A3DyCl6 auf; sie alle enthalten isolierte Koordinationspolyeder.Ternary Chlorides in the Systems ACl/DyCl3 (A = Cs, Rb, K)The phase diagrams of the pseudobinary systems ACl/DyCl3 (A = Cs, Rb, K) were investigated by DTA. With all alkali metals compounds A3DyCl6 (elpasolite family) and Ady2Cl7 are formed. Compounds A2DyCl5 exist only with Cs (Cs2DyCl5-type) and K (K2PrCl5-type). By solution calorimetry the formation enthalpies of the ternary chlorides from (nACl + DyCl3) were measured and ‘synproportionation enthalpies’ for the formation from the compounds, adjacent in the phase diagrams, calculated. K3DyCl6 is the only compound, which is formed with a loss in lattice enthalpy. E.m.f. measurements in dependence on the temperature have revealed that, as for the other compounds A3DyCl6, a remarkable gain in entropy exists, which stabilizes K3DyCl6 at T ≧ 312 K. This entropy gain correlates with the existence of isolated DyCl63− octahedra." @default.
- W2128343667 created "2016-06-24" @default.
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- W2128343667 date "1998-02-01" @default.
- W2128343667 modified "2023-10-17" @default.
- W2128343667 title "Ternäre Chloride in den Systemen ACl/YCl3 (A = Cs, Rb, K, Na)" @default.
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- W2128343667 doi "https://doi.org/10.1002/(sici)1521-3749(199802)624:2<342::aid-zaac342>3.0.co;2-k" @default.
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