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• W2128351631 abstract "Herein we describe three Ga(8) compounds that feature gallium atoms in an oxidation state of 1.25 with normal valent 2e-2c bonding. Their structures and the influence of their ligands (phosphorus and nitrogen atoms directly bonded to the Ga(8) moieties) are discussed on the basis of DFT calculations, providing an insight into a probable mechanism for insertion reactions between GaX and GaX(3) species that lead to a reaction cascade via halides like Ga(2)X(4) and Ga(5)X(7) to Ga(8)X(10) and Ga(8)X(12) (2-), respectively. Finally, the Ga(8) cores of the three title compounds were compared with the topology of carbon atoms in C(8) alkanes." @default.
• W2128351631 created "2016-06-24" @default.
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• W2128351631 date "2007-05-25" @default.
• W2128351631 modified "2023-10-18" @default.
• W2128351631 title "Discussion on the Formation and Bonding in Three [Ga8R10] Compounds: The Diversity in Classical GaGa Bonds" @default.
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• W2128351631 doi "https://doi.org/10.1002/chem.200601632" @default.
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