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- W2128423596 abstract "The thermodynamics of anion exchange of the systems NO3−/Cl−, NO3−/Br− and NO3−/SCN− in hydrous ceria in mixed (methanolic) solutions has been studied. NO3− is preferred by ceria to Cl− and SCN− due to the enthalpy term while the NO3−/Br− exchange is entropy directed. The addition of 30 and 60% (w/w) methanol decreases ΔG0 and increases ΔH0 and ΔS0 of the exchange of Cl− for NO3− in hydrous ceria and thus the increase of selectivity constant is due to the entropy term. In the case of the exchange of Br− for NO3−, a decrease of the selectivity constant occurs at 30 and 60% (w/w) methanol which is due to entropy changes. Also, on addition of alcohol up to 60% (w/w), in the case of the exchange of SCN− for NO3−, the increase of ΔG0 and the decreases of ΔH0 and ΔS0 are due to entropy changes. Changes in ion solvent interactions in the aqueous phase lead to an increase in ΔH0 and ΔS0, and the decrease in ΔH0 and ΔS0 on the addition of methanol is due to the change in the solid phase interactions." @default.
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- W2128423596 date "1998-04-01" @default.
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- W2128423596 title "Effect of methyl alcohol additions on thermodynamic constants of anion exchange properties of hydrous ceria" @default.
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