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• W2128474492 abstract "Abstract Unprecedented functionalized products with an η 4 ‐P 5 ring are obtained by the reaction of [Cp*Fe(η 5 ‐P 5 )] ( 1 ; Cp*=η 5 ‐C 5 Me 5 ) with different nucleophiles. With LiCH 2 SiMe 3 and LiNMe 2 , the monoanionic products [Cp*Fe(η 4 ‐P 5 CH 2 SiMe 3 )] − and [Cp*Fe(η 4 ‐P 5 NMe 2 )] − , respectively, are formed. The reaction of 1 with NaNH 2 leads to the formation of the trianionic compound [{Cp*Fe(η 4 ‐P 5 )} 2 N] 3− , whereas the reaction with LiPH 2 yields [Cp*Fe(η 4 ‐P 5 PH 2 )] − as the main product, with {[Cp*Fe(η 4 ‐P 5 )] 2 PH} 2− as a byproduct. The calculated energy profile of the reactions provides a rationale for the formation of the different products." @default.
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• W2128474492 date "2014-06-04" @default.
• W2128474492 modified "2023-10-18" @default.
• W2128474492 title "Functionalization of a<i>cyclo</i>-P₅Ligand by Main-Group Element Nucleophiles" @default.
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• W2128474492 doi "https://doi.org/10.1002/anie.201403581" @default.
• W2128474492 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24895298" @default.
• W2128474492 hasPublicationYear "2014" @default.
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