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- W2128593685 abstract "The dissolution kinetics of two samples of commercial ground Fontainebleau sand consisting of > 99.6% quartz are studied at 25 °C in constant ionic strength conditions and in the pH range 4.5–10.5. The strong pH dependence of the reaction rate is attributed to changes in the surface speciation of quartz. The ionization of the surface silanol groups is investigated using potentiometric methods and the results are compared with literature data using a simple surface speciation model that accounts for the effects of the electrical double layer on the hydrogen ion activity. The surface speciation model produces titration curves in good agreement with the experimental data and offers an interpretation of the relationship between the density of ionized groups, [SiO–(s)], and pH." @default.
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- W2128593685 date "1992-01-01" @default.
- W2128593685 modified "2023-09-24" @default.
- W2128593685 title "Investigation of the pH dependence of the kinetics of quartz dissolution at 25 °C" @default.
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- W2128593685 doi "https://doi.org/10.1039/ft9928800233" @default.
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