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- W2128601944 abstract "Here, the synthesis, characterization, and photovoltaic properties of four new donor–acceptor copolymers are reported. These copolymers are based on 4,4-difluoro-cyclopenta[2,1-b:3,4-b′] dithiophene as an acceptor unit and various donor moieties: 4,4-dialkyl derivatives of 4H-cyclopenta[2,1-b:3,4-b′]dithiophene and its silicon analog, dithieno[3,2-b:2′,3′-d]-silol. These copolymers have an almost identical bandgap of 1.7 eV and have a HOMO energy level that varies from −5.34 to −5.73 eV. DSC and X-ray diffraction (XRD) investigations reveal that linear octyl substituents promote the formation of ordered layered structures, while branched 2-ethylhexyl substituents lead to amorphous materials. Polymer solar cells based on these copolymers as donor and PC61BM as acceptor components yield a power conversion efficiency of 2.4%." @default.
- W2128601944 created "2016-06-24" @default.
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- W2128601944 date "2013-07-29" @default.
- W2128601944 modified "2023-10-16" @default.
- W2128601944 title "Novel Cyclopentadithiophene-Based D-A Copolymers for Organic Photovoltaic Cell Applications" @default.
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- W2128601944 doi "https://doi.org/10.1002/macp.201300328" @default.
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