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- W2128666576 abstract "The bromination of 2,3-diarylcyclopent-2-en-1-ones under various conditions has been studied. It was found that depending on the brominating reagent and nature of solvent the bromine atom can be introduced at the 4- or 5-position of the ethene “bridge”, as well as into the aryl moieties. Aryl group bromination is accomplished with such reagents as molecular bromine, N-bromosuccinimide, or tetrabutylammonium tribromide. 5-Bromocyclopentenones with very high efficiency can be obtained by the reaction with copper(II) bromide in methanol, while 4-bromoketones are prepared in n-propyl acetate. The developed methods can be highly useful for the synthesis of bromo-substituted 2-cyclopenten-1-ones and their close analogues, which are important synthons in organic synthesis and for the preparation of a variety of useful substances." @default.
- W2128666576 created "2016-06-24" @default.
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- W2128666576 date "2012-09-07" @default.
- W2128666576 modified "2023-09-26" @default.
- W2128666576 title "Regio- and Chemoselective Bromination of 2,3-Diarylcyclopent-2-en-1-ones" @default.
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- W2128666576 doi "https://doi.org/10.1021/jo301474j" @default.
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