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- W2128751982 abstract "High-quality mass spectrometry data of the oscillatory behavior of CO oxidation on SiO(2) supported Pt-nanoparticles at atmospheric pressure have been acquired as a function of pressure, coverage, gas composition and nanoparticle size. The oscillations are self-sustained for several days at constant temperature, pressure and CO/O(2) ratio. The frequency of the oscillations is very well defined and increases over time. The oscillation frequency is furthermore strongly temperature dependent with increasing temperature resulting in increasing frequency. A plausible mechanism for the oscillations is proposed based on an oxidation-reduction cycle of the nanoparticles which change the rate of CO oxidation on the particles." @default.
- W2128751982 created "2016-06-24" @default.
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- W2128751982 date "2013-01-01" @default.
- W2128751982 modified "2023-10-16" @default.
- W2128751982 title "Self-sustained carbon monoxide oxidation oscillations on size-selected platinum nanoparticles at atmospheric pressure" @default.
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- W2128751982 doi "https://doi.org/10.1039/c2cp43684a" @default.
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