Matches in SemOpenAlex for { <https://semopenalex.org/work/W2128894610> ?p ?o ?g. }
- W2128894610 endingPage "15822" @default.
- W2128894610 startingPage "15818" @default.
- W2128894610 abstract "A Z-selective rhodium-catalyzed hydrothiolation of 1,3-disubstituted allenes and subsequent oxidation towards the corresponding allylic sulfones is described. Using the bidentate 1,4-bis(diphenylphosphino)butane (dppb) ligand, Z/E-selectivities up to >99:1 were obtained. The highly atom-economic desymmetrization reaction tolerates functionalized aromatic and aliphatic thiols. Additionally, a variety of symmetric internal allenes, as well as unsymmetrically disubstituted substrates were well tolerated, thus resulting in high regioselectivities. Starting from chiral but racemic 1,3-disubstituted allenes a dynamic kinetic resolution (DKR) could be achieved by applying (S,S)-Me-DuPhos as the chiral ligand. The desired Z-allylic sulfones were obtained in high yields and enantioselectivities up to 96 % ee." @default.
- W2128894610 created "2016-06-24" @default.
- W2128894610 creator A5050374573 @default.
- W2128894610 creator A5067624195 @default.
- W2128894610 date "2015-09-29" @default.
- W2128894610 modified "2023-10-17" @default.
- W2128894610 title "<i>Z</i> ‐Selective Hydrothiolation of Racemic 1,3‐Disubstituted Allenes: An Atom‐Economic Rhodium‐Catalyzed Dynamic Kinetic Resolution" @default.
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