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- W2128971404 abstract "Abstract Photochemical oxidative desulfurization of thiophene with tetrabutylammonium bromide (TBAB) as phase transfer catalyst was studied. The effects of the TBAB addition and pH on the desulfurization yield of thiophene were investigated. The cycle model of desulfurization of thiophene with TBAB was proposed. The results show that the desulfurization yield of thiophene in n-octane is 80.6% for a 2-hr photoirradiation under the conditions of air flow at 150 mL/min, V (n-octane):V (water) = 1:1, pH = 12, and 0.1 g of TBAB as catalyst. The photooxidation kinetics of thiophene is first-order with rate constant of 0.5702 hr−1 and half-life of 1.22 hr." @default.
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- W2128971404 date "2010-06-11" @default.
- W2128971404 modified "2023-10-01" @default.
- W2128971404 title "The Photooxidative Desulfurization of Thiophene with Tetrabutylammonium Bromide as a Phase Transfer Catalyst" @default.
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- W2128971404 doi "https://doi.org/10.1080/10916460903058186" @default.
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