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- W2128991570 abstract "The kinetics of oxidation of metol (N-methyl-p-aminophenol) by thallium(III) have been studied in a perchloric acid medium. This organic compound is employed extensively in photographic work. The stoichiometry of the reaction is represented by: C 6 H 4 (OH)NHCH 3 + Tl III → C 6 H 4 (O)NCH 3 + Tl I + 2H + . The kinetics indicate the rate law: k' = Kk [metal]/1 + K [metol] where k' is the pseudo-first-order rate constant. The rate constants and thermodynamic parameters for the rate-limiting step have been evaluated" @default.
- W2128991570 created "2016-06-24" @default.
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- W2128991570 date "1994-03-01" @default.
- W2128991570 modified "2023-09-26" @default.
- W2128991570 title "Kinetics and mechanism of electron-transfer reaction of aquothallium(III) and coordinated thallium(III). Oxidation of metol with thallium(III) in acid perchlorate medium" @default.
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- W2128991570 doi "https://doi.org/10.1002/poc.610070303" @default.
- W2128991570 hasPublicationYear "1994" @default.
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