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- W2129075093 startingPage "1341" @default.
- W2129075093 abstract "Paramagnetic resonance of single crystals of [Cr(NH 3 ) 6 ]C1 3 diluted with [Cr(NH 3 ) 6 ]Cl 3 has been studied at 9.2 kMc/sec and at room temperature. There are three inequivalent complexes [Cr(NH 3 ) 6 ] 3+ that have their x axis of the crystal field all parallel to the b axis of the crystal (monoclinic) but the y and z axes in different orientations. Parameters D and E in the spin Hamiltonian are also different for the three Cr 3+ ions. The apparent spin-orbit coupling in the crystal is estimated from the g value and is found to be in between the values for [Cr(H 2 O) 6 ] 3+ and [Cr(CN) 6 ] 3- . A method is described in the appendix to evaluate E / D from the angles for the static magnetic field where the two transitions M =3/2↔1/2 and -1/2↔-3/2 coincide, and formulas are derived for the resonance fields for S =3/2 which are correct to the sixth order of perturbation." @default.
- W2129075093 created "2016-06-24" @default.
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- W2129075093 date "1962-09-01" @default.
- W2129075093 modified "2023-09-24" @default.
- W2129075093 title "Paramagnetic Resonance of Diluted [Cr(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>3</sub>" @default.
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- W2129075093 doi "https://doi.org/10.1143/jpsj.17.1341" @default.
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