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• W2129157434 abstract "This article describes an account of some of our polyoxometalate (POM)-based research, we have been doing in our laboratory last several years. There are several well-defined POM cluster anions, that are structurally characterized. We have chosen Anderson-type of heteropolyanion [Al(OH)6Mo6O18]3 − and explored its linking propensity in different dimensions using ‘s’, ‘d’ and ‘f’ block elements as linkers. We have demonstrated how a lanthanide linker provides a new pathway in forming a two-dimensional linked {As8V14} system [{Ln(H2O)6}2As8V14O42(SO3)]n · 8nH2O, that is derived from discrete {As8V14} cluster containing compound (NH4)6[As8V14O42(SO3)]. A polyoxometalate compound has been described in which a reduced tungstovanadate–heteropolyanion clusters get linked via capped V = O groups into one-dimensional chains. All these systems have already been reported elsewhere. The last portion of this article will be described by a new system [3-ampH]6[V10O28] · 2H2O having discrete molecular structure and extended supramolecular structure." @default.
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• W2129157434 date "2011-03-01" @default.
• W2129157434 modified "2023-09-24" @default.
• W2129157434 title "Polyoxometalates: Toward new materials" @default.
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• W2129157434 doi "https://doi.org/10.1007/s12039-011-0115-2" @default.
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