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- W2129293411 endingPage "12823" @default.
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- W2129293411 abstract "A new methodology allowing preparation of a linear “unsaturated” [3]rotaxane consisting of an axis incorporating more coordination sites than threaded rings was developed. It was based on the preliminary synthesis of a “saturated” [5]rotaxane consisting of a four-chelating site axis threaded through four macrocyclic components, two of them being cleavable rings incorporating a lactone function and the two others being “secure” non-cleavable rings. The stoppering reaction was based on click chemistry. Subsequently, cleavage and removal of the two lactone-containing macrocycles from the [5]rotaxane in basic medium afforded the desired “unsaturated” [3]rotaxane in quantitative yield." @default.
- W2129293411 created "2016-06-24" @default.
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- W2129293411 creator A5075109017 @default.
- W2129293411 date "2013-08-09" @default.
- W2129293411 modified "2023-10-03" @default.
- W2129293411 title "Use of Cleavable Coordinating Rings as Protective Groups in the Synthesis of a Rotaxane with an Axis that Incorporates More Chelating Groups Than Threaded Macrocycles" @default.
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- W2129293411 doi "https://doi.org/10.1002/chem.201301717" @default.
- W2129293411 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23934923" @default.
- W2129293411 hasPublicationYear "2013" @default.
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