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- W2129338520 abstract "Hydrofluoroethers are shown to alkylate tertiary amines readily under solvent-free conditions, affording valuable tetraalkylammonium perfluoroalkoxides bearing α-fluorines. The reaction of R(F)CF2-OCH3 (R(F)=CF2CF3, CF2CF2CF3, and CF(CF3)2) with NR(1)R(2)R(3) produces twenty new α-perfluoroalkoxides, [(CH3)NR(1)R(2)R(3)][R(F)CF2O] under mild conditions. These α-perfluoroalkoxides are easy to handle, thermally stable, and can be used for the perfluoroalkoxylation of benzyl bromides." @default.
- W2129338520 created "2016-06-24" @default.
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- W2129338520 date "2015-01-22" @default.
- W2129338520 modified "2023-10-17" @default.
- W2129338520 title "A Convenient Route to Tetraalkylammonium Perfluoroalkoxides from Hydrofluoroethers" @default.
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- W2129338520 doi "https://doi.org/10.1002/anie.201410639" @default.
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- W2129338520 hasPublicationYear "2015" @default.
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