FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2129347615> ?p ?o ?g. }

• W2129347615 endingPage "1345" @default.
• W2129347615 startingPage "1339" @default.
• W2129347615 abstract "The synthesis and spectroscopic properties of Cr(bpy)(chrySQ)(chryCat), a complex containing chromium(III) metal ion and chrysenequinone ligand in its partially reduced (chrySQ) and fully reduced (chryCat) forms, are described. The complex has been prepared by two different routes from Cr(CO)6 and Cr(chrySQ)3. Variable temperature magnetic susceptibility measurements indicated a strong antiferromagnetic coupling between Cr(III) (S=3/2) and chrysenesemiquinone radical (S=1/2), giving a magnetic coupling constant J=-342 cm(-1). Ligand-based redox couples were observed in the electrochemical studies that consist of quasi-reversible chrySQ/chryCat and bpy/bpy*- reductions and chryCat/chrySQ oxidation at negative potentials and irreversible chrySQ/chryBQ oxidation at positive potential. However, the metal was inert in the studied potential range. The electronic spectra of the complex revealed interesting properties. In addition to interaligand pi-pi* and n-pi* transitions, other bands corresponding to Cr(t(2g))-->chrySQ(pi*) and Cr(t(2g))-->bpy(pi*) metal-to-ligand charge-transfer MLCT transitions were observed. The infrared spectral analysis was informative in assigning the vibrations due to SQ and Cat ligands. Also, it was a useful tool in confirming the coordination of bpy ligand to chromium metal ion." @default.
• W2129347615 created "2016-06-24" @default.
• W2129347615 creator A5045638928 @default.
• W2129347615 date "2007-08-01" @default.
• W2129347615 modified "2023-09-23" @default.
• W2129347615 title "Synthesis and spectroscopic studies on chromium(III) complex containing mixed-valence chrysenesemiquinone-chrysenecatecholate ligands and 2,2′-bipyridine coligand" @default.
• W2129347615 cites W1666271728 @default.
• W2129347615 cites W1964312268 @default.
• W2129347615 cites W1966270045 @default.
• W2129347615 cites W1970663163 @default.
• W2129347615 cites W1977899114 @default.
• W2129347615 cites W1979106815 @default.
• W2129347615 cites W1990995282 @default.
• W2129347615 cites W1993409143 @default.
• W2129347615 cites W1997030277 @default.
• W2129347615 cites W1997530181 @default.
• W2129347615 cites W2006653538 @default.
• W2129347615 cites W2009030163 @default.
• W2129347615 cites W2017978654 @default.
• W2129347615 cites W2020049491 @default.
• W2129347615 cites W2020288580 @default.
• W2129347615 cites W2039371681 @default.
• W2129347615 cites W2042125178 @default.
• W2129347615 cites W2043698546 @default.
• W2129347615 cites W2056119707 @default.
• W2129347615 cites W2056793392 @default.
• W2129347615 cites W2061566044 @default.
• W2129347615 cites W2063944502 @default.
• W2129347615 cites W2088505060 @default.
• W2129347615 cites W2088866503 @default.
• W2129347615 cites W2157080936 @default.
• W2129347615 cites W2951260845 @default.
• W2129347615 cites W3004904520 @default.
• W2129347615 cites W3102526660 @default.
• W2129347615 cites W2471912030 @default.
• W2129347615 doi "https://doi.org/10.1016/j.saa.2006.10.021" @default.
• W2129347615 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17126590" @default.
• W2129347615 hasPublicationYear "2007" @default.
• W2129347615 type Work @default.
• W2129347615 sameAs 2129347615 @default.
• W2129347615 citedByCount "2" @default.
• W2129347615 countsByYear W21293476152012 @default.
• W2129347615 countsByYear W21293476152013 @default.
• W2129347615 crossrefType "journal-article" @default.
• W2129347615 hasAuthorship W2129347615A5045638928 @default.
• W2129347615 hasConcept C106773901 @default.
• W2129347615 hasConcept C115624301 @default.
• W2129347615 hasConcept C116569031 @default.
• W2129347615 hasConcept C145148216 @default.
• W2129347615 hasConcept C147789679 @default.
• W2129347615 hasConcept C161790260 @default.
• W2129347615 hasConcept C16889073 @default.
• W2129347615 hasConcept C168900304 @default.
• W2129347615 hasConcept C170493617 @default.
• W2129347615 hasConcept C17525397 @default.
• W2129347615 hasConcept C178790620 @default.
• W2129347615 hasConcept C179104552 @default.
• W2129347615 hasConcept C185592680 @default.
• W2129347615 hasConcept C2779336533 @default.
• W2129347615 hasConcept C511782168 @default.
• W2129347615 hasConcept C52859227 @default.
• W2129347615 hasConcept C544153396 @default.
• W2129347615 hasConcept C55493867 @default.
• W2129347615 hasConcept C55904794 @default.
• W2129347615 hasConcept C8010536 @default.
• W2129347615 hasConceptScore W2129347615C106773901 @default.
• W2129347615 hasConceptScore W2129347615C115624301 @default.
• W2129347615 hasConceptScore W2129347615C116569031 @default.
• W2129347615 hasConceptScore W2129347615C145148216 @default.
• W2129347615 hasConceptScore W2129347615C147789679 @default.
• W2129347615 hasConceptScore W2129347615C161790260 @default.
• W2129347615 hasConceptScore W2129347615C16889073 @default.
• W2129347615 hasConceptScore W2129347615C168900304 @default.
• W2129347615 hasConceptScore W2129347615C170493617 @default.
• W2129347615 hasConceptScore W2129347615C17525397 @default.
• W2129347615 hasConceptScore W2129347615C178790620 @default.
• W2129347615 hasConceptScore W2129347615C179104552 @default.
• W2129347615 hasConceptScore W2129347615C185592680 @default.
• W2129347615 hasConceptScore W2129347615C2779336533 @default.
• W2129347615 hasConceptScore W2129347615C511782168 @default.
• W2129347615 hasConceptScore W2129347615C52859227 @default.
• W2129347615 hasConceptScore W2129347615C544153396 @default.
• W2129347615 hasConceptScore W2129347615C55493867 @default.
• W2129347615 hasConceptScore W2129347615C55904794 @default.
• W2129347615 hasConceptScore W2129347615C8010536 @default.
• W2129347615 hasIssue "5" @default.
• W2129347615 hasLocation W21293476151 @default.
• W2129347615 hasLocation W21293476152 @default.
• W2129347615 hasOpenAccess W2129347615 @default.
• W2129347615 hasPrimaryLocation W21293476151 @default.
• W2129347615 hasRelatedWork W1989404362 @default.
• W2129347615 hasRelatedWork W2059065238 @default.
• W2129347615 hasRelatedWork W2069193002 @default.
• W2129347615 hasRelatedWork W2106633646 @default.
• W2129347615 hasRelatedWork W2129347615 @default.
• W2129347615 hasRelatedWork W2793665360 @default.
• W2129347615 hasRelatedWork W2805258436 @default.
• W2129347615 hasRelatedWork W3043445788 @default.

• next