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- W2129441849 abstract "A ligand rotation which orientates the oxygen atom of an amide group towards or away from a neighbouring metal centre provides rotamers A and B with E° potentials which differ by 150 mV; oxidation of the metal centre of B switches the system from a state in which there is a small difference in the relative populations of the rotamers to one in which the cis-amide conformation greatly predominates; this new metallocycle system can be viewed as a pseudo-proline with redox sensitive rotameric properties." @default.
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- W2129441849 date "1997-01-01" @default.
- W2129441849 modified "2023-10-18" @default.
- W2129441849 title "Ligand rotamers and redox isomerism: metallo-pseudo-prolines" @default.
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- W2129441849 doi "https://doi.org/10.1039/a706634a" @default.
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