FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2129510347> ?p ?o ?g. }

• W2129510347 endingPage "8543" @default.
• W2129510347 startingPage "8530" @default.
• W2129510347 abstract "Creating structure-property correlations at different distance scales is one of the important challenges to the rational design of molecular gelators. Here, a series of dihydroxylated derivatives of long-chain fatty acids, derived from three naturally occurring molecules-oleic, erucic and ricinoleic acids-are investigated as gelators of a wide variety of liquids. Conclusions about what constitutes a more (or less!) efficient gelator are based upon analyses of a variety of thermal, structural, molecular modeling, and rheological results. Correlations between the manner of molecular packing in the neat solid or gel states of the gelators and Hansen solubility data from the liquids leads to the conclusion that diol stereochemistry, the number of carbon atoms separating the two hydroxyl groups, and the length of the alkanoic chains are the most important structural parameters controlling efficiency of gel formation for these gelators. Some of the diol gelators are as efficient or even more efficient than the well-known, excellent gelator, (R)-12-hydroxystearic acid; others are much worse. The ability to form extensive intermolecular H-bonding networks along the alkyl chains appears to play a key role in promoting fiber growth and, thus, gelation. In toto, the results demonstrate how the efficiency of gelation can be modulated by very small structural changes and also suggest how other structural modifications may be exploited to create efficient gelators." @default.
• W2129510347 created "2016-06-24" @default.
• W2129510347 creator A5000561706 @default.
• W2129510347 creator A5036490827 @default.
• W2129510347 creator A5053656477 @default.
• W2129510347 creator A5077104032 @default.
• W2129510347 creator A5086186754 @default.
• W2129510347 date "2015-04-29" @default.
• W2129510347 modified "2023-10-07" @default.
• W2129510347 title "Structural and Solubility Parameter Correlations of Gelation Abilities for Dihydroxylated Derivatives of Long‐Chain, Naturally Occurring Fatty Acids" @default.
• W2129510347 cites W1963531331 @default.
• W2129510347 cites W1965098846 @default.
• W2129510347 cites W1967376910 @default.
• W2129510347 cites W1970375711 @default.
• W2129510347 cites W1972288290 @default.
• W2129510347 cites W1973001784 @default.
• W2129510347 cites W1975938982 @default.
• W2129510347 cites W1977721948 @default.
• W2129510347 cites W1980726649 @default.
• W2129510347 cites W1984433223 @default.
• W2129510347 cites W1985298358 @default.
• W2129510347 cites W1992889865 @default.
• W2129510347 cites W1994323230 @default.
• W2129510347 cites W1996896232 @default.
• W2129510347 cites W2002363341 @default.
• W2129510347 cites W2006780738 @default.
• W2129510347 cites W2011859111 @default.
• W2129510347 cites W2013865111 @default.
• W2129510347 cites W2015887716 @default.
• W2129510347 cites W2021721619 @default.
• W2129510347 cites W2024245204 @default.
• W2129510347 cites W2026008620 @default.
• W2129510347 cites W2027183586 @default.
• W2129510347 cites W2028046413 @default.
• W2129510347 cites W2034541607 @default.
• W2129510347 cites W2037962969 @default.
• W2129510347 cites W2038945733 @default.
• W2129510347 cites W2039331082 @default.
• W2129510347 cites W2042217361 @default.
• W2129510347 cites W2044055746 @default.
• W2129510347 cites W2045849117 @default.
• W2129510347 cites W2046577852 @default.
• W2129510347 cites W2048709359 @default.
• W2129510347 cites W2051662094 @default.
• W2129510347 cites W2055137886 @default.
• W2129510347 cites W2055504282 @default.
• W2129510347 cites W2064215568 @default.
• W2129510347 cites W2065736816 @default.
• W2129510347 cites W2068883734 @default.
• W2129510347 cites W2074070959 @default.
• W2129510347 cites W2075172153 @default.
• W2129510347 cites W2077561678 @default.
• W2129510347 cites W2077945479 @default.
• W2129510347 cites W2079480065 @default.
• W2129510347 cites W2082654497 @default.
• W2129510347 cites W2085700284 @default.
• W2129510347 cites W2086345888 @default.
• W2129510347 cites W2090540178 @default.
• W2129510347 cites W2091966957 @default.
• W2129510347 cites W2093863659 @default.
• W2129510347 cites W2094923026 @default.
• W2129510347 cites W2095138127 @default.
• W2129510347 cites W2098672372 @default.
• W2129510347 cites W2099492782 @default.
• W2129510347 cites W2106078261 @default.
• W2129510347 cites W2106997657 @default.
• W2129510347 cites W2115392854 @default.
• W2129510347 cites W2126383912 @default.
• W2129510347 cites W2137102551 @default.
• W2129510347 cites W2148458781 @default.
• W2129510347 cites W2148695875 @default.
• W2129510347 cites W2150195378 @default.
• W2129510347 cites W2161174878 @default.
• W2129510347 cites W2167980511 @default.
• W2129510347 cites W2168553366 @default.
• W2129510347 cites W2171655616 @default.
• W2129510347 cites W2204604131 @default.
• W2129510347 cites W2271070329 @default.
• W2129510347 cites W2312237736 @default.
• W2129510347 cites W2319605335 @default.
• W2129510347 cites W2326595205 @default.
• W2129510347 cites W2328289209 @default.
• W2129510347 cites W2329363801 @default.
• W2129510347 cites W2333988885 @default.
• W2129510347 cites W2492289546 @default.
• W2129510347 cites W54074587 @default.
• W2129510347 doi "https://doi.org/10.1002/chem.201500096" @default.
• W2129510347 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25926104" @default.
• W2129510347 hasPublicationYear "2015" @default.
• W2129510347 type Work @default.
• W2129510347 sameAs 2129510347 @default.
• W2129510347 citedByCount "18" @default.
• W2129510347 countsByYear W21295103472016 @default.
• W2129510347 countsByYear W21295103472017 @default.
• W2129510347 countsByYear W21295103472018 @default.
• W2129510347 countsByYear W21295103472019 @default.
• W2129510347 countsByYear W21295103472020 @default.
• W2129510347 countsByYear W21295103472021 @default.

• next