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- W2129589957 abstract "A reinvestigation of the constitution of green and brown complex iron cyanides, often reputed to be FeIIIFeIII(CN)6, has been undertaken. Infra-red absorption spectrophotometry by means of which the valence state of iron in the [Fe(CN)6]n−-ions may be identified, was used as main diagnostic tool. It was established that iron(III)-hexacyanoferrate(III) had not hitherto been prepared in the pure state as the hexacyanoferrate ions in this compound are readily reduced, under the influence of the water present during precipitation, whereby CN-ligands are oxidised and hydrolysed to CO2 and NH4+. The reaction is furthermore maintained in dry samples by water molecules included in the lattice.Die Konstitution der grunen und braunen Eisenkomplexcyanide, welche oft als FeIIIFeIII(CN)6, angesehen wurden, ist neu untersucht worden. Durch Absorptionsspektrophotometrie im infraroten Gebiet last sich die Oxydationsstufe in den [Fe(CN)6]n−-Ionen feststellen. Eisen(III)-hexacyanoferrat(III) konnte bisher noch nicht in reinem Zustand hergestellt werden, da die Hexacyanoferrationen dieser Verbindung schon wahrend der Fallung sehr leicht unter dem Einflus von Wasser reduziert werden, wobei durch Oxydation und Hydrolyse aus CN-Liganden CO2 und NH4+ entstehen. Die Reaktion lauft sogar im trockenen Zustand als Folge des eingebauten Kristallwassers weiter." @default.
- W2129589957 created "2016-06-24" @default.
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- W2129589957 date "1965-03-01" @default.
- W2129589957 modified "2023-09-26" @default.
- W2129589957 title "On the existence and Autoreduction of Iron(III)-hexacyanoferrate(III)" @default.
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- W2129589957 doi "https://doi.org/10.1002/zaac.19653360114" @default.
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