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- W2129702014 abstract "[74379-76-3] C12H13LiN (MW 178.20)InChI = 1S/C12H13N.Li/c1-13(2)12-9-5-7-10-6-3-4-8-11(10)12;/h3-9H,1-2H3;/q-1;+1InChIKey = DFINHRZFIGWVDX-UHFFFAOYSA-N(reductive lithiations of thioacetals;2 generation of α-lithio ethers,3 α-lithio silanes;6 synthesis of α-trialkylsilyl ketones;7 generation of allyllithiums;1b desulfurization10)Alternate Name: LDMAN.Solubility: generated in THF.Preparative Methods: anhydrous THF and cleaned lithium metal ribbon are cooled to between −58 and −52 °C using an acetone/dry ice bath; 1-N,N-dimethylaminonaphthalene is added slowly; the appearance of the dark green radical anion is evident within 10 min, but complete conversion to LDMAN takes 5 h at −55 °C.Handling, Storage, and Precautions: LDMAN must be prepared and used right away at temperature below −52 °C. No method of titration has been developed." @default.
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- W2129702014 date "2015-04-01" @default.
- W2129702014 modified "2023-09-26" @default.
- W2129702014 title "Lithium 1-(Dimethylamino)naphthalenide" @default.
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- W2129702014 doi "https://doi.org/10.1002/047084289x.rl103.pub2" @default.
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