Matches in SemOpenAlex for { <https://semopenalex.org/work/W2129776883> ?p ?o ?g. }
Showing items 1 to 59 of
59
with 100 items per page.
- W2129776883 endingPage "92" @default.
- W2129776883 startingPage "73" @default.
- W2129776883 abstract "Poly(diaryl diazosulfide)s were synthesized from aromatic bisdiazonium ions and benzene-1,3-dithiol via interfacial polycondensation. Number-average molecular weights Mn in the range of 3400 to 11700 were determined by gel permeation chromatography (GPC). The new polymer class is distinguished by high photosensitivity and low thermostability. First order kinetics during photolysis of nearly all polymers and model compounds under investigation was observed by means of UV spectroscopy. Polymer degradation upon irradiation was verified by GPC measurements. Thermal decay was followed by differential scanning calorimetry (DSC). Polydiaryldiazosulfide wurden durch Grenzflächenpolykondensation aus aromatischen Bisdiazoniumionen und Benzol-1,3-dithiol erhalten. Auf diese Weise wurden Molekulargewichte Mn von 3400 bis 11700 erreicht (GPC). Die neue Polymerklasse zeichnet sich durch hohe Photolabilität und relativ geringe Thermostabilität aus. Mittels UV-Spektroskopie wurde die Photolyse von Modellver-bindungen und Polymeren verfolgt, wobei in nahezu allen Fällen ein Zerfall 1. Ordnung beobachtet wurde. Der photochemische Kettenabbau konnte durch GPC-Untersuchungen verfolgt werden. Die thermische Stabilität der polymeren Diazosulfide wurde durch DSC-Messungen untersucht." @default.
- W2129776883 created "2016-06-24" @default.
- W2129776883 creator A5004920178 @default.
- W2129776883 creator A5009017155 @default.
- W2129776883 creator A5057888461 @default.
- W2129776883 creator A5075565254 @default.
- W2129776883 date "1995-06-01" @default.
- W2129776883 modified "2023-10-14" @default.
- W2129776883 doi "https://doi.org/10.1002/apmc.1995.052280107" @default.
- W2129776883 hasPublicationYear "1995" @default.
- W2129776883 type Work @default.
- W2129776883 sameAs 2129776883 @default.
- W2129776883 citedByCount "2" @default.
- W2129776883 crossrefType "journal-article" @default.
- W2129776883 hasAuthorship W2129776883A5004920178 @default.
- W2129776883 hasAuthorship W2129776883A5009017155 @default.
- W2129776883 hasAuthorship W2129776883A5057888461 @default.
- W2129776883 hasAuthorship W2129776883A5075565254 @default.
- W2129776883 hasConcept C121332964 @default.
- W2129776883 hasConcept C178790620 @default.
- W2129776883 hasConcept C185592680 @default.
- W2129776883 hasConcept C188027245 @default.
- W2129776883 hasConcept C2776617069 @default.
- W2129776883 hasConcept C2777691172 @default.
- W2129776883 hasConcept C39519442 @default.
- W2129776883 hasConcept C521977710 @default.
- W2129776883 hasConcept C63179538 @default.
- W2129776883 hasConcept C97355855 @default.
- W2129776883 hasConceptScore W2129776883C121332964 @default.
- W2129776883 hasConceptScore W2129776883C178790620 @default.
- W2129776883 hasConceptScore W2129776883C185592680 @default.
- W2129776883 hasConceptScore W2129776883C188027245 @default.
- W2129776883 hasConceptScore W2129776883C2776617069 @default.
- W2129776883 hasConceptScore W2129776883C2777691172 @default.
- W2129776883 hasConceptScore W2129776883C39519442 @default.
- W2129776883 hasConceptScore W2129776883C521977710 @default.
- W2129776883 hasConceptScore W2129776883C63179538 @default.
- W2129776883 hasConceptScore W2129776883C97355855 @default.
- W2129776883 hasIssue "1" @default.
- W2129776883 hasLocation W21297768831 @default.
- W2129776883 hasOpenAccess W2129776883 @default.
- W2129776883 hasPrimaryLocation W21297768831 @default.
- W2129776883 hasRelatedWork W1988875377 @default.
- W2129776883 hasRelatedWork W2019596777 @default.
- W2129776883 hasRelatedWork W2067950880 @default.
- W2129776883 hasRelatedWork W2077904478 @default.
- W2129776883 hasRelatedWork W2121106221 @default.
- W2129776883 hasRelatedWork W2171358112 @default.
- W2129776883 hasRelatedWork W2372448337 @default.
- W2129776883 hasRelatedWork W2808094540 @default.
- W2129776883 hasRelatedWork W4306180729 @default.
- W2129776883 hasRelatedWork W601207934 @default.
- W2129776883 hasVolume "228" @default.
- W2129776883 isParatext "false" @default.
- W2129776883 isRetracted "false" @default.
- W2129776883 magId "2129776883" @default.
- W2129776883 workType "article" @default.