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- W2129831639 endingPage "2015" @default.
- W2129831639 startingPage "2015" @default.
- W2129831639 abstract "The tris(3-t-butyl-5-methylpyrazolyl)hydroborato and tris(2-pyridylthio)methyl derivatives, [TpBut,Me]ZnOCO2H and [κ4-Tptm]ZnOCO2H, are the first pair of terminal zinc bicarbonate complexes to be structurally characterized by using X-ray diffraction. In both cases, the bicarbonate ligand coordinates in a unidentate manner, comparable to that in human carbonic anhydrase I. While the bicarbonate complex [κ4-Tptm]ZnOCO2H is obtained by treatment of {[κ3-Tptm]Zn(μ–OH)}2 with CO2 in the presence of water, the bridging carbonate complex [Tptm]Zn(μ-CO3)Zn[Tptm] is obtained in the absence of water. The reactivity of {[κ3-Tptm]Zn(μ–OH)}2 towards CO2 is sufficiently high that the carbonate complex is obtained upon exposure to air." @default.
- W2129831639 created "2016-06-24" @default.
- W2129831639 creator A5046851967 @default.
- W2129831639 creator A5072093741 @default.
- W2129831639 date "2012-01-01" @default.
- W2129831639 modified "2023-10-10" @default.
- W2129831639 title "Structural characterization of zinc bicarbonate compounds relevant to the mechanism of action of carbonic anhydrase" @default.
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- W2129831639 doi "https://doi.org/10.1039/c2sc20167d" @default.
- W2129831639 hasPublicationYear "2012" @default.
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