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• W2130023552 abstract "Isotopic sensitivity is reported in both the formation and the above ambient temperature annealing behaviour of lamellar microphases in C30:C36 paraffin solid solutions. The time resolved small angle neutron scattering from a 1:1 C30H62:C36D74 mixture and its complementary pair 1:1 C D :C H has been studied. Upon quenching such mixtures from the melt; the solid solution so formed nucleates spontaneously to a ‘long period’ microphase. The two systems differ in that for 1:1 C30D62:C36H74 there is also strong diffraction at Q = 0·136 A-1 associated with C36H74 enrichment of the solid solution or a separate phase. Both processes are sensitive to the isotopic composition of the mixture. For both systems the long period scattering from a quenched liquid mixture develops in periods of hours at ambient temperature. Heating the aged microphase structures to temperatures above about 43°C causes them to disappear, but again isotropic sensitivity is noted. It is concluded that the effects are largely kinetic in origin, in agreement with earlier IR studies on intralamellar microaggregation in this system." @default.
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• W2130023552 date "1997-08-01" @default.
• W2130023552 modified "2023-09-25" @default.
• W2130023552 title "Isotope effects on the microphase separation of paraffin mixtures" @default.
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• W2130023552 doi "https://doi.org/10.1080/002689797170770" @default.
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