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- W2130060174 abstract "The product distribution for the reactions CH4++CD4, CH3+ + CD4, C2H4++C2D4, and their isotopic complements are determined as a function of reactant ion kinetic energy over the range from thermal energies to 10 eV. The reaction of CH4+ with the parent neutral proceeds both via proton transfer and hydrogen atom abstraction accompanied by approximately 10% hydrogen atom exchange during reaction. The reactions CH3++CD4 and C2H4++C2D4 are shown to proceed with isotopic scrambling of the hydrogen atoms over the entire kinetic energy range from thermal energies to 10 eV. Several endothermic channels are observed at high kinetic energies for the reaction C2H4++C2D4 including the production of C2H2+, C2H3+, C2H5+, and C3H3+ ions." @default.
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- W2130060174 date "1972-05-15" @default.
- W2130060174 modified "2023-10-18" @default.
- W2130060174 title "Hydrogen Atom Scrambling in Ion‐Molecule Reactions of Methane and Ethylene" @default.
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- W2130060174 doi "https://doi.org/10.1063/1.1676996" @default.
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