FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2130291271> ?p ?o ?g. }

• W2130291271 endingPage "1370" @default.
• W2130291271 startingPage "1361" @default.
• W2130291271 abstract "Di-1-alkynyltin compounds (1) react with triorganoboranes R3B [2a (REt), 2b (RiPr)] to give (η21-alkynyl)tin compounds 3 (REt) and 4 (RiPr) in which a cationic three-coordinate tin centre is stabilized by intramolecular side-on coordination to the CC bond of an alkynylborate fragment. An X-ray analysis of 3e, prepared from Me2Sn(CCiPr)2 (1e) and Et3B, proves the coordination of the tin atom to the CC bond as well as a weak BC bond. An important dynamic process, i.e. exchange of the alkynyl group between boron and tin, is shown by 11B and 119Sn NMR at variable temperature. Most of the intermediates 3 react with an excess of Et3B by a second intramolecular 1,1-ethyloboration to dialkenyltin derivatives 7 which readily rearrange to the 3-stannolenes 8. Without an excess of Et3B, intramolecular 1,1-vinyloboration (leading to the stannoles 5) competes with intramolecular 1,1-ethyloboration (leading to 1-stanna-4-bora-2,5-cyclohexadienes 9). The latter route is preferred in the case of most of the intermediates 4 (intramolecular 1,1-isopropyloboration) and affords the six-membered rings 10 (RiPr). 11B-and 13C-NMR data indicate that the heterocycles 9 (REt) adopt a flatter conformation than 10 (RiPr)." @default.
• W2130291271 created "2016-06-24" @default.
• W2130291271 creator A5008991088 @default.
• W2130291271 creator A5032477595 @default.
• W2130291271 creator A5079183378 @default.
• W2130291271 date "1993-06-01" @default.
• W2130291271 modified "2023-10-14" @default.
• W2130291271 title "Routes to Stannoles, Stannolenes and 1‐Stanna‐4‐bora‐2,5‐cyclohexadienes – Crystal Structure of a Triorganotin Cation Stabilized by π1‐Coordination" @default.
• W2130291271 cites W1503885849 @default.
• W2130291271 cites W1506020938 @default.
• W2130291271 cites W1509353719 @default.
• W2130291271 cites W1537789258 @default.
• W2130291271 cites W1541853681 @default.
• W2130291271 cites W1572865540 @default.
• W2130291271 cites W1586970462 @default.
• W2130291271 cites W1602734318 @default.
• W2130291271 cites W1964409377 @default.
• W2130291271 cites W1966825945 @default.
• W2130291271 cites W1969686426 @default.
• W2130291271 cites W1971737140 @default.
• W2130291271 cites W1991093393 @default.
• W2130291271 cites W1996709929 @default.
• W2130291271 cites W2003474443 @default.
• W2130291271 cites W2008948600 @default.
• W2130291271 cites W2009399730 @default.
• W2130291271 cites W2013169614 @default.
• W2130291271 cites W2017693931 @default.
• W2130291271 cites W2020454981 @default.
• W2130291271 cites W2028079978 @default.
• W2130291271 cites W2035400525 @default.
• W2130291271 cites W2043905998 @default.
• W2130291271 cites W2047750550 @default.
• W2130291271 cites W2052150506 @default.
• W2130291271 cites W2054000361 @default.
• W2130291271 cites W2056275621 @default.
• W2130291271 cites W2058392681 @default.
• W2130291271 cites W2062455487 @default.
• W2130291271 cites W2064333966 @default.
• W2130291271 cites W2066641436 @default.
• W2130291271 cites W2077037131 @default.
• W2130291271 cites W2087081368 @default.
• W2130291271 cites W2087823838 @default.
• W2130291271 cites W2089353068 @default.
• W2130291271 cites W2091837271 @default.
• W2130291271 cites W2092699905 @default.
• W2130291271 cites W2097738518 @default.
• W2130291271 cites W2101052025 @default.
• W2130291271 cites W2106172156 @default.
• W2130291271 cites W2107555574 @default.
• W2130291271 cites W2115785082 @default.
• W2130291271 cites W2119150442 @default.
• W2130291271 cites W2156611906 @default.
• W2130291271 cites W2164933264 @default.
• W2130291271 cites W2211459621 @default.
• W2130291271 cites W2316995136 @default.
• W2130291271 cites W2323447291 @default.
• W2130291271 cites W2331013077 @default.
• W2130291271 cites W2483307774 @default.
• W2130291271 cites W2497812861 @default.
• W2130291271 cites W2949834981 @default.
• W2130291271 cites W2950591610 @default.
• W2130291271 doi "https://doi.org/10.1002/cber.19931260615" @default.
• W2130291271 hasPublicationYear "1993" @default.
• W2130291271 type Work @default.
• W2130291271 sameAs 2130291271 @default.
• W2130291271 citedByCount "82" @default.
• W2130291271 countsByYear W21302912712012 @default.
• W2130291271 countsByYear W21302912712013 @default.
• W2130291271 countsByYear W21302912712014 @default.
• W2130291271 countsByYear W21302912712015 @default.
• W2130291271 countsByYear W21302912712016 @default.
• W2130291271 countsByYear W21302912712018 @default.
• W2130291271 countsByYear W21302912712019 @default.
• W2130291271 countsByYear W21302912712020 @default.
• W2130291271 countsByYear W21302912712021 @default.
• W2130291271 crossrefType "journal-article" @default.
• W2130291271 hasAuthorship W2130291271A5008991088 @default.
• W2130291271 hasAuthorship W2130291271A5032477595 @default.
• W2130291271 hasAuthorship W2130291271A5079183378 @default.
• W2130291271 hasConcept C155647269 @default.
• W2130291271 hasConcept C178790620 @default.
• W2130291271 hasConcept C183882617 @default.
• W2130291271 hasConcept C185592680 @default.
• W2130291271 hasConcept C525849907 @default.
• W2130291271 hasConcept C71240020 @default.
• W2130291271 hasConcept C75079739 @default.
• W2130291271 hasConceptScore W2130291271C155647269 @default.
• W2130291271 hasConceptScore W2130291271C178790620 @default.
• W2130291271 hasConceptScore W2130291271C183882617 @default.
• W2130291271 hasConceptScore W2130291271C185592680 @default.
• W2130291271 hasConceptScore W2130291271C525849907 @default.
• W2130291271 hasConceptScore W2130291271C71240020 @default.
• W2130291271 hasConceptScore W2130291271C75079739 @default.
• W2130291271 hasIssue "6" @default.
• W2130291271 hasLocation W21302912711 @default.
• W2130291271 hasOpenAccess W2130291271 @default.
• W2130291271 hasPrimaryLocation W21302912711 @default.
• W2130291271 hasRelatedWork W1148372108 @default.

• next