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- W2130409832 abstract "Cation exchange reactions in clays and soils have repeatedly been shown in the literature to be hysteretic during typical laboratory experiments. Yet all existing models of solute transport in soils and aquifers assume these reactions to be thermodynamically reversible. To remedy this situation a mathematical description of cation exchange hysteresis is needed. In the present research isotherms were obtained for a K-Mg exchange on Camp Berteau montmorillonite. Scanning curves were also measured, corresponding to arbitrary reversals of the direction of the exchange reactions. Three different Preisach-hysteresis models were used to describe the scanning curves. The fit of each hysteresis model to the experimental observations was analysed in terms of the features of the model itself and, from a physical viewpoint, in terms of a recently proposed conceptual model of cation exchange hysteresis." @default.
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- W2130409832 date "1996-09-01" @default.
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- W2130409832 title "Cation exchange hysteresis scanning curves: mathematical description and interpretation" @default.
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- W2130409832 doi "https://doi.org/10.1111/j.1365-2389.1996.tb01408.x" @default.
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