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- W2130481041 abstract "The thermodynamics of ideal and non-ideal solutions is applied to nickel hydroxide, the electrochemically active material in the positive electrode of a nickel battery, to provide theoretical insight into the reversible potential as a function of the state-of-discharge. The models were fit to experimental discharge curves to obtain the activity-coefficient parameters and the standard potential over a temperature range from 5 to 55°C. The two-parameter activity coefficient models perform significantly better than the Nernst equation and one-parameter Margules at all temperatures, thus suggesting that the insertion of the protons into the lattice occurs in an ordered, non-random fashion. The standard potential decreases linearly with temperature by 0.84 mV/K. The thermodynamic expressions and parameters given here enable one to predict the reversible potential of nickel hydroxide as a function of temperature and state-of-discharge." @default.
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- W2130481041 date "1998-06-01" @default.
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- W2130481041 title "Thermodynamic considerations of the reversible potential for the nickel electrode" @default.
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- W2130481041 doi "https://doi.org/10.1016/s0013-4686(97)10181-5" @default.
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