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• W2130516130 abstract "Systematic measurements and analyses of surface nucleation and growth of μ-cordierite on diamond-polished surfaces and on fractured surfaces of cordierite glasses containing 0.3, 1.2, 3.4, 6.2 and 8.1 wt% TiO2 were carried out. All the glasses exhibit surface nucleation, however, the glass having 8.1 wt% TiO2 also exhibits volume nucleation. The maximum surface nucleation rate is located at a temperature considerably higher than the maximum volume nucleation rate. Both surface and volume crystallization occur by heterogeneous nucleation. The average nucleus/substrate wetting angles, θ, were estimated from surface and volume nucleation measurements. The widely different values of θ indicate that the active catalyzing sites are different for surface and volume crystallization. It is likely that Al2TiO5 crystals induce volume crystallization of μ-cordierite, while surface crystallization is affected by TiO2, defects and relicts of polishing power. Nucleation on fractured surfaces was induced mainly by solid particles, most likely by broken glass particles. The crystal growth velocity of μ-cordierite crystals is well fitted by the 2D-surface nucleation growth model." @default.
• W2130516130 created "2016-06-24" @default.
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• W2130516130 date "1999-04-01" @default.
• W2130516130 modified "2023-10-11" @default.
• W2130516130 title "Surface and volume nucleation and growth in TiO2–cordierite glasses" @default.
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• W2130516130 doi "https://doi.org/10.1016/s0022-3093(99)00007-1" @default.
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