Matches in SemOpenAlex for { <https://semopenalex.org/work/W2130534080> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2130534080 endingPage "633" @default.
- W2130534080 startingPage "626" @default.
- W2130534080 abstract "The zerovalent iron complex Fe(PMe 3 ) 2 (t-BuNC) 3 undergoes thermal cleavage of the CN bond to give Fe(PMe 3 ) 2 (t-BuNC) 2 (H)(CN) and isobutylene. The reaction follows first order kinetics, and addition of the hydrogen-atom donor 1,4-cyclohexadiene leads to the preferential formation of isobutane rather than isobutylene. Mechanistic studies are consistent with a rate determining homolysis of the CN bond, giving rise to tert-butyl radicals.Key words: iron, isocyanide, elimination, CN cleavage." @default.
- W2130534080 created "2016-06-24" @default.
- W2130534080 creator A5009330355 @default.
- W2130534080 creator A5044532043 @default.
- W2130534080 date "2005-06-01" @default.
- W2130534080 modified "2023-10-03" @default.
- W2130534080 title "Kinetics and mechanism of dealkylation of coordinated isocyanide in Fe(PMe<sub>3</sub>)<sub>2</sub>(<i>t</i>-BuNC)<sub>3</sub>" @default.
- W2130534080 cites W1912100387 @default.
- W2130534080 cites W1997080726 @default.
- W2130534080 cites W2019077191 @default.
- W2130534080 cites W2030986270 @default.
- W2130534080 cites W2048743616 @default.
- W2130534080 cites W2060646569 @default.
- W2130534080 cites W2074948934 @default.
- W2130534080 cites W2081525230 @default.
- W2130534080 cites W2095038836 @default.
- W2130534080 cites W2323934330 @default.
- W2130534080 cites W2335217515 @default.
- W2130534080 doi "https://doi.org/10.1139/v05-023" @default.
- W2130534080 hasPublicationYear "2005" @default.
- W2130534080 type Work @default.
- W2130534080 sameAs 2130534080 @default.
- W2130534080 citedByCount "14" @default.
- W2130534080 countsByYear W21305340802012 @default.
- W2130534080 countsByYear W21305340802013 @default.
- W2130534080 countsByYear W21305340802015 @default.
- W2130534080 countsByYear W21305340802016 @default.
- W2130534080 countsByYear W21305340802020 @default.
- W2130534080 countsByYear W21305340802023 @default.
- W2130534080 crossrefType "journal-article" @default.
- W2130534080 hasAuthorship W2130534080A5009330355 @default.
- W2130534080 hasAuthorship W2130534080A5044532043 @default.
- W2130534080 hasConcept C121332964 @default.
- W2130534080 hasConcept C127413603 @default.
- W2130534080 hasConcept C139066938 @default.
- W2130534080 hasConcept C148898269 @default.
- W2130534080 hasConcept C155647269 @default.
- W2130534080 hasConcept C15920480 @default.
- W2130534080 hasConcept C161790260 @default.
- W2130534080 hasConcept C175156509 @default.
- W2130534080 hasConcept C175689099 @default.
- W2130534080 hasConcept C178790620 @default.
- W2130534080 hasConcept C185592680 @default.
- W2130534080 hasConcept C187320778 @default.
- W2130534080 hasConcept C2776906966 @default.
- W2130534080 hasConcept C2777010268 @default.
- W2130534080 hasConcept C2778861962 @default.
- W2130534080 hasConcept C3044715 @default.
- W2130534080 hasConcept C43369102 @default.
- W2130534080 hasConcept C44578547 @default.
- W2130534080 hasConcept C521977710 @default.
- W2130534080 hasConcept C62520636 @default.
- W2130534080 hasConcept C71240020 @default.
- W2130534080 hasConcept C75473681 @default.
- W2130534080 hasConceptScore W2130534080C121332964 @default.
- W2130534080 hasConceptScore W2130534080C127413603 @default.
- W2130534080 hasConceptScore W2130534080C139066938 @default.
- W2130534080 hasConceptScore W2130534080C148898269 @default.
- W2130534080 hasConceptScore W2130534080C155647269 @default.
- W2130534080 hasConceptScore W2130534080C15920480 @default.
- W2130534080 hasConceptScore W2130534080C161790260 @default.
- W2130534080 hasConceptScore W2130534080C175156509 @default.
- W2130534080 hasConceptScore W2130534080C175689099 @default.
- W2130534080 hasConceptScore W2130534080C178790620 @default.
- W2130534080 hasConceptScore W2130534080C185592680 @default.
- W2130534080 hasConceptScore W2130534080C187320778 @default.
- W2130534080 hasConceptScore W2130534080C2776906966 @default.
- W2130534080 hasConceptScore W2130534080C2777010268 @default.
- W2130534080 hasConceptScore W2130534080C2778861962 @default.
- W2130534080 hasConceptScore W2130534080C3044715 @default.
- W2130534080 hasConceptScore W2130534080C43369102 @default.
- W2130534080 hasConceptScore W2130534080C44578547 @default.
- W2130534080 hasConceptScore W2130534080C521977710 @default.
- W2130534080 hasConceptScore W2130534080C62520636 @default.
- W2130534080 hasConceptScore W2130534080C71240020 @default.
- W2130534080 hasConceptScore W2130534080C75473681 @default.
- W2130534080 hasIssue "6-7" @default.
- W2130534080 hasLocation W21305340801 @default.
- W2130534080 hasOpenAccess W2130534080 @default.
- W2130534080 hasPrimaryLocation W21305340801 @default.
- W2130534080 hasRelatedWork W2008054716 @default.
- W2130534080 hasRelatedWork W2073318348 @default.
- W2130534080 hasRelatedWork W2076287940 @default.
- W2130534080 hasRelatedWork W2081786465 @default.
- W2130534080 hasRelatedWork W2121845975 @default.
- W2130534080 hasRelatedWork W2130534080 @default.
- W2130534080 hasRelatedWork W2161702604 @default.
- W2130534080 hasRelatedWork W2171771246 @default.
- W2130534080 hasRelatedWork W2756091089 @default.
- W2130534080 hasRelatedWork W4206027330 @default.
- W2130534080 hasVolume "83" @default.
- W2130534080 isParatext "false" @default.
- W2130534080 isRetracted "false" @default.
- W2130534080 magId "2130534080" @default.
- W2130534080 workType "article" @default.