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- W2130543047 abstract "The reorientation of a water molecule is important for a host of phenomena, ranging over--in an only partial listing--the key dynamic hydrogen-bond network restructuring of water itself, aqueous solution chemical reaction mechanisms and rates, ion transport in aqueous solution and membranes, protein folding, and enzymatic activity. This review focuses on water reorientation and related dynamics in pure water, and for aqueous solutes with hydrophobic, hydrophilic, and amphiphilic character, ranging from tetra-methylurea to halide ions and amino acids. Attention is given to the application of theory, simulation, and experiment in the probing of these dynamics, in usefully describing them, and in assessing the description. Special emphasis is placed on a novel sudden, large-amplitude jump mechanism for water reorientation, which contrasts with the commonly assumed Debye rotational diffusion mechanism, characterized by small-amplitude angular motion. Some open questions and directions for further research are also discussed." @default.
- W2130543047 created "2016-06-24" @default.
- W2130543047 creator A5000113075 @default.
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- W2130543047 creator A5063997177 @default.
- W2130543047 creator A5072018035 @default.
- W2130543047 creator A5072105936 @default.
- W2130543047 date "2011-05-05" @default.
- W2130543047 modified "2023-10-14" @default.
- W2130543047 title "Reorientation and Allied Dynamics in Water and Aqueous Solutions" @default.
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