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- W2130544946 abstract "Reaction of K2[RuCl5(H2O)] with N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethylenediamine (L1) in ethanol gave cis-[RuIIIL1Cl2]+ and then cis-[RuIIIL1(Cl)(H2O)]2+ upon reaction with AgI in water. The structure of cis-[RuIIIL1(Cl)(H2O)][ClO4]2·2H2O has been established by X-ray crystallography: space group Pbca, a= 10.863(1), b= 21.548(2), c= 21.912(2)A. The measured Ru-Cl and Ru-OH2 distances are 2.307(4)A and 2.070(9)A respectively. A cyclic voltammogram of cis-[RuIIIL1(Cl)-(H2O)]2+ in 0.1 mol dm–3 CF3CO2H shows three reversible/quasi-reversible couples at 1.29, 0.93 and 0.23 V vs. saturated calomel electrode assigned to the couples RuV-RuIV, RuIV-RuIII and RuIII-RuII. The complex cis-[RuIIIL1(Cl)(H2O)]2+ is an active catalyst for the electrochemical oxidation of alcohols and tetrahydrofuran. The second-order rate constant for the oxidation of benzyl alcohol by electrochemically generated cis-[RuVL1(Cl)O]2+ is estimated to be 8.4 × 104 dm3 mol–1 s–1." @default.
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- W2130544946 date "1991-01-01" @default.
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- W2130544946 title "Synthesis, electrochemistry and X-ray crystal structure of cis-[Ru<sup>III</sup>L<sup>1</sup>(Cl)(H<sub>2</sub>O)][ClO<sub>4</sub>]<sub>2</sub>·2H<sub>2</sub>O [L<sup>1</sup>=N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethylenediamine]; electrochemical oxidation of alcohols and tetrahydrofuran by cis-[Ru<sup>V</sup>L<sup>1</sup>(Cl)O]<sup>2+</sup>" @default.
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- W2130544946 doi "https://doi.org/10.1039/dt9910001909" @default.
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