Matches in SemOpenAlex for { <https://semopenalex.org/work/W2130578052> ?p ?o ?g. }
Showing items 1 to 64 of
64
with 100 items per page.
- W2130578052 endingPage "1327" @default.
- W2130578052 startingPage "1322" @default.
- W2130578052 abstract "The oxidation by cobaltic perchlorate of the acids Ph[CH2]n·CO2H (n= 2–5) have been studied in aqueous methyl cyanide. Both kinetic measurements and product analyses substantiate the mechanism of Part VI viz. RCO2H +{Co(H2O)6}3+⇌{RCO·O·Co(H2O)5}2++ H3O+(1), RCO·O·CoIII(H2O)5→ R·+ CO2+ CoII(H2O)5(2) The organic radicals from equation (2) can be trapped by the addition of bromoform and estimated as the corresponding alkyl bromides. Further oxidation of these radicals leads to stepwise degradation to lower alcohols and aldehydes; the latter are oxidised sufficiently slowly for their isolation to be possible." @default.
- W2130578052 created "2016-06-24" @default.
- W2130578052 creator A5033939173 @default.
- W2130578052 creator A5064787989 @default.
- W2130578052 creator A5085290264 @default.
- W2130578052 date "1968-01-01" @default.
- W2130578052 modified "2023-10-17" @default.
- W2130578052 title "Oxidations of organic compounds by cobalt salts. Part XI. Kinetic and product studies of oxidations of some ω-phenylalkanecarboxylic acids" @default.
- W2130578052 doi "https://doi.org/10.1039/j29680001322" @default.
- W2130578052 hasPublicationYear "1968" @default.
- W2130578052 type Work @default.
- W2130578052 sameAs 2130578052 @default.
- W2130578052 citedByCount "1" @default.
- W2130578052 crossrefType "journal-article" @default.
- W2130578052 hasAuthorship W2130578052A5033939173 @default.
- W2130578052 hasAuthorship W2130578052A5064787989 @default.
- W2130578052 hasAuthorship W2130578052A5085290264 @default.
- W2130578052 hasConcept C139066938 @default.
- W2130578052 hasConcept C145148216 @default.
- W2130578052 hasConcept C155647269 @default.
- W2130578052 hasConcept C178790620 @default.
- W2130578052 hasConcept C179104552 @default.
- W2130578052 hasConcept C184651966 @default.
- W2130578052 hasConcept C185592680 @default.
- W2130578052 hasConcept C2778455166 @default.
- W2130578052 hasConcept C2779905697 @default.
- W2130578052 hasConcept C2780709120 @default.
- W2130578052 hasConcept C2781144210 @default.
- W2130578052 hasConcept C515602321 @default.
- W2130578052 hasConcept C77176794 @default.
- W2130578052 hasConceptScore W2130578052C139066938 @default.
- W2130578052 hasConceptScore W2130578052C145148216 @default.
- W2130578052 hasConceptScore W2130578052C155647269 @default.
- W2130578052 hasConceptScore W2130578052C178790620 @default.
- W2130578052 hasConceptScore W2130578052C179104552 @default.
- W2130578052 hasConceptScore W2130578052C184651966 @default.
- W2130578052 hasConceptScore W2130578052C185592680 @default.
- W2130578052 hasConceptScore W2130578052C2778455166 @default.
- W2130578052 hasConceptScore W2130578052C2779905697 @default.
- W2130578052 hasConceptScore W2130578052C2780709120 @default.
- W2130578052 hasConceptScore W2130578052C2781144210 @default.
- W2130578052 hasConceptScore W2130578052C515602321 @default.
- W2130578052 hasConceptScore W2130578052C77176794 @default.
- W2130578052 hasIssue "0" @default.
- W2130578052 hasLocation W21305780521 @default.
- W2130578052 hasOpenAccess W2130578052 @default.
- W2130578052 hasPrimaryLocation W21305780521 @default.
- W2130578052 hasRelatedWork W1965686416 @default.
- W2130578052 hasRelatedWork W1969264711 @default.
- W2130578052 hasRelatedWork W1998128627 @default.
- W2130578052 hasRelatedWork W2028236172 @default.
- W2130578052 hasRelatedWork W2034619173 @default.
- W2130578052 hasRelatedWork W2077455633 @default.
- W2130578052 hasRelatedWork W2085031349 @default.
- W2130578052 hasRelatedWork W2319842176 @default.
- W2130578052 hasRelatedWork W2470477812 @default.
- W2130578052 hasRelatedWork W69366923 @default.
- W2130578052 hasVolume "0" @default.
- W2130578052 isParatext "false" @default.
- W2130578052 isRetracted "false" @default.
- W2130578052 magId "2130578052" @default.
- W2130578052 workType "article" @default.