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- W2130578666 endingPage "11379" @default.
- W2130578666 startingPage "11379" @default.
- W2130578666 abstract "Sixteen N,N′-bis(salicylidene)diamines of common formula (o-OHC6H4CN–)2Z [Z = o-C6H4 (1a), m-C6H4 (2a), p-C6H4 (3a), Ø (4a), CH2(p-C6H4)2 (5a), O(p-C6H4)2 (6a), S(p-C6H4)2 (7a), SO2(p-C6H4)2 (8a)] and N,N′-bis(5-bromosalicylidene)diamines of common formula (2-OH-(5-Br)C6H3CN–)2Z [Z = o-C6H4 (1b), m-C6H4 (2b), p-C6H4 (3), Ø (4b), CH2(p-C6H4)2 (5b), O(p-C6H4)2 (6b), S(p-C6H4)2 (7b), SO2(p-C6H4)2 (8b)] have been synthesized and characterized by elemental analysis, X-ray powder diffraction, NMR, diffuse reflectance, Raman, IR and fluorescence spectroscopy. Molecular structures of 2a, 6a, 7a, 8a and 4b were elucidated by single crystal X-ray diffraction. Their structures are stabilized by two intramolecular hydrogen bonds and weak intermolecular π⋯π stacking interactions. All molecules are thermochromic, while molecules 2a and 2b exclusively display photochromism upon irradiation at 450 and 365 nm, respectively, which is reversible and exhibits relatively slow thermal relaxation." @default.
- W2130578666 created "2016-06-24" @default.
- W2130578666 creator A5014911221 @default.
- W2130578666 creator A5021398373 @default.
- W2130578666 creator A5078415011 @default.
- W2130578666 date "2012-01-01" @default.
- W2130578666 modified "2023-10-01" @default.
- W2130578666 title "Solid-state thermo- and photochromism in N,N′-bis(5-X-salicylidene)diamines (X = H, Br)" @default.
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- W2130578666 doi "https://doi.org/10.1039/c2ra21631k" @default.
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