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• W2130751098 abstract "The occurrence of intramolecular 1,4-hydride shifts from alkane carbon to oxocarbonium carbon in acyl cations has been demonstrated in the long-lived 4-methyl- and 3,4-dimethylpentanoyl cations in FSO3HSbF5. Strong, though not conclusive evidence has been obtained for an intramolecular 1,5-hydride shift in the hexanoyl cation. Attempts to observe a 1,5-hydride shift in 5-methyl-hexanoyl ion were unsuccessful owing to the occurrence of side reactions; in FSO3HSbF5 this cation undergoes intermolecular hydride abstraction. The 1,4 shifts are much faster than 1,2- or 1,3-hydride shifts to oxocarbonium carbon, as demonstrated by the absence of the latter reactions, under comparable conditions, in the pentanoyl, 3-methylpentanoyl and 2-methylbutanoyl ions. The differences in the relative rates of 1,2- 1,3- and 1,4-hydride shifts between oxocarbonium and alkylcarbonium ions are discussed." @default.
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• W2130751098 date "1973-01-01" @default.
• W2130751098 modified "2023-10-17" @default.
• W2130751098 title "Hydride transfer reactions. I: Intramolecular hydride shifts in alkyloxocarbonium ions" @default.
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• W2130751098 doi "https://doi.org/10.1002/recl.19730920509" @default.
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