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- W2130841899 abstract "Nonstoichiometric cerium oxide-based catalysts were investigated for SO2 reduction by CO to elemental sulfur, CO oxidation, and complete methane oxidation. Nanocrystalline processing by inert gas condensation was exploited for its unique potential to generate nonstoichiometric ultrahighly dispersed oxides. Nanocrystalline CeO2−x materials, pure or doped with 10 at.% La or 15 at.% Cu, were generated by magnetron sputtering from pure or mixed metal targets, followed by controlled oxidation. These materials allowed us to investigate the effects of oxide nonstoichiometry and dopants on catalytic activity in oxidation reactions. The nonstoichiometric materials were characterized by X-ray diffraction, nitrogen adsorption porosimetry, and X-ray photoelectron spectroscopy. Catalytic properties were studied in a packed-bed reactor and compared to materials of similar composition prepared by coprecipitation. In general, the nonstoichiometric CeO2-based materials exhibited greater catalytic activity than precipitated ultrafine materials. The light-off temperatures for SO2 reduction by CO, CO oxidation, and CH4 oxidation were 100-180°C lower for the nanocrystalline pure and La-doped CeO2−x catalysts than for the respective precipitated materials. The Cu-doped form of both types of catalysts possessed comparable activity. The nonstoichiometric materials did not show a hysteresis behavior in the activity profile for SO2 reduction by CO, unlike the precipitated catalysts. They further demonstrated a remarkable stability against CO2 poisoning in this reaction. The differences between the nanocrystalline and the precipitated materials are discussed in terms of the stoichiometry of these oxide catalysts." @default.
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- W2130841899 date "1995-11-01" @default.
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- W2130841899 title "Redox Activity of Nonstoichiometric Cerium Oxide-Based Nanocrystalline Catalysts" @default.
- W2130841899 doi "https://doi.org/10.1006/jcat.1995.1266" @default.
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