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• W2130861014 abstract "This work describes the preparation of a selective receptor for the rapid, selective, and sensitive electrochemical flow injection analysis of zinc using air stable lipid films supported on a methacrylate polymer on a glass fibre filter with incorporated artificial receptor. The selective receptor was synthesised by transformation of the –OH groups of resorcin4 Weiss, JH, Sensi, SL and Koh, JY. 2000. Trends Pharmacol. Sci., 21: 395[Crossref], [PubMed], [Web of Science ®] , [Google Scholar]arene receptor into phosphoryl groups. These lipid films were supported on a methylacrylate polymer (i.e. methacrylic acid was the functional monomer for the polymerisation, ethylene glycol dimethacrylate was used as the crosslinker and 2,2′-azobis-2-methylpropionitrile as an initiator). A minisensor device was constructed for the electrochemical flow injection analysis of zinc based on air stabilised lipid films supported on a polymer. The device can sense the analyte in a drop (75 µL) of sample. Zinc was injected into flowing streams of a carrier electrolyte solution. A complex formation between the calix4 Weiss, JH, Sensi, SL and Koh, JY. 2000. Trends Pharmacol. Sci., 21: 395[Crossref], [PubMed], [Web of Science ®] , [Google Scholar]arene phosphoryl receptor and zinc takes place. This enhances the pre-concentration of zinc at the lipid membrane surface which in turn causes dynamic alterations of the electrostatic fields and phase structure of membranes; as a result ion current transients were obtained and the magnitude of these signals was correlated to the substrate concentration. The response times were ca 5 s and zinc was determined at concentration levels of nanomolar. The analytical curve was linear in the concentration range 1.00 × 10−7 − 1.20 × 10−6 M with detection limit of 5.00 × 10−8 M and a relative standard deviation lower than 4%. The effect of potent interferences included a wide range of other metals. As an analytical demonstration, trace concentrations of Zn(II) were successfully detected in real samples of waters without any laborious and time-consuming treatment." @default.
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• W2130861014 date "2009-03-15" @default.
• W2130861014 modified "2023-10-11" @default.
• W2130861014 title "Development of an electrochemical chemosensor for the rapid detection of zinc based on air stable lipid films with incorporated calix4arene phosphoryl receptor" @default.
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• W2130861014 doi "https://doi.org/10.1080/03067310802578952" @default.
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