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• W2130868963 abstract "Abstract Four novel coordination polymers were solvothermally synthesized from metal(II) salts (the metals being Mn, Ca, and Sr) and 2,5‐dihydroxyterephthalic acid (H 4 dhtp), and their crystal structures were determined by single‐crystal X‐ray diffraction analysis. Of the two different types of functional group of the organic linker, only the carboxylic acid has been deprotonated on formation of the compounds. The manganese compound Mn(H 2 dhtp)(H 2 O) 2 , CPO‐26‐Mn, contains octahedrally coordinated metal atoms in a three‐dimensional framework. It is isostructural with the previously reported magnesium compound CPO‐26‐Mg. The heavier alkaline earth elements calcium and strontrium exhibit higher coordination numbers in their compounds. Calcium was found to form two compounds depending on reaction conditions, Ca(H 2 dhtp)(H 2 O) 2 , CPO‐20, and Ca(H 2 dhtp), CPO‐21. Both structures consist of three‐dimensional networks. CPO‐20 contains dimeric edge‐sharing calcium coordination polyhedra, whereas in CPO‐21 the octacoordinate calcium coordination polyhedra are linked by common edges to straight one‐dimensional chains. The crystal structure of Sr(H 2 dhtp)(H 2 O), CPO‐22, is similar to that of CPO‐21. Again, the coordination polyhedra are condensed by shared edges into one‐dimensional chains. However, because the strontium atom is nonacoordinate, with the additional ligand being the water molecule, the chains are corrugated in this case." @default.
• W2130868963 created "2016-06-24" @default.
• W2130868963 creator A5031433543 @default.
• W2130868963 creator A5040133782 @default.
• W2130868963 creator A5086369320 @default.
• W2130868963 date "2009-10-01" @default.
• W2130868963 modified "2023-10-09" @default.
• W2130868963 title "Coordination Polymers Based on the 2,5‐Dihydroxyterephthalate Ion and Alkaline Earth Metal (Ca, Sr) and Manganese Cations " @default.
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• W2130868963 doi "https://doi.org/10.1002/zaac.200900348" @default.
• W2130868963 hasPublicationYear "2009" @default.
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